26 November 2019

[Thin-films] – Nanotubes to equip ceramic coatings with heat radiation control

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Ceramic nanotubes - Codex International

Researchers at Purdue University have engineered ceramic “nanotubes” that behave as thermal antennas, offering control over the spectrum and direction of high-temperature heat radiation.
The work is published in Nano Letters (“High-Temperature Polaritons in Ceramic Nanotube Antennas”). An illustration of the ceramic nanotubes will be featured as the journal’s supplementary cover in a forthcoming issue.
“By controlling radiation at these high temperatures, we can increase the lifetime of the coating. The performance of the engine would also increase because it could be kept hotter with more isolation for longer periods of time,” said Zubin Jacob, an associate professor of electrical and computer engineering at Purdue.
The work is part of a larger search in the field for a wide range of materials that can withstand higher temperatures. In 2016, Jacob’s team developed a thermal “metamaterial” – made of tungsten and hafnium oxide – that controls heat radiation with the intention of improving how waste heat is harvested from power plants and factories.
A new class of ceramics would expand on ways to more efficiently use heat radiation.
Jacob’s team, in collaboration with Purdue professors Luna Lu and Tongcang Li, built nanotubes out of an emerging ceramic material called boron nitride, known for its high thermal stability.
These boron nitride nanotubes control radiation through oscillations of light and matter, called polaritons, inside the ceramic material. High temperatures excite the polaritons, which the nanotubes – as antennas – then couple efficiently to outgoing heat radiation.
The antennas could bring the ability to accelerate the radiation, perform enhanced cooling of a system or send information in very specific directions or wavelengths, Jacob said.
The researchers plan to engineer more ceramic materials with polaritonic features for a host of different applications.
“Polaritonic ceramics can be game changing and we want them to be used widely,” Jacob said.

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